Self-penetrating and interpenetrating 3D metal-organic frameworks constructed from 4-(4-carboxyphenoxy)-phthalic acid and N-donor auxiliary ligands |
| |
| Authors: | He Wu Wu-Juan Sun Wen-Jie Zhao Ting Shi Xu-Zhao Liao Xu-Wu Yang |
| |
| Affiliation: | 1.Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science,Northwest University,Xi’an,China;2.Department of Biochemical Engineering,Xianyang Vocational Technical college,Xianyang,China |
| |
| Abstract: | ![]()
Two new interesting entangled structures, namely, [Ni1.5(L)(bpy)2(H2O)3] n · 3nH2O (I) and [Cd3(L)2(bbi)2]n · nH2O (II)(where H3L is 4-(4-carboxyphenoxy)-phthalic acid, bpy is 4,4′-bipyridine, and bbi is 1,1′-(1,4-butanediyl)bis(imidazole)) have been synthesized and characterized by elemental analysis (EA), infrared spectra (IR), X-ray powder diffraction (XRPD), solid fluorescence and thermogravimetric analysis (TGA). Single-crystal X-ray diffraction analysis revealed that complex I possesses a 3D self-penetrating framework constructed from ladder-like and fishbone-like subunits. Complex II shows a 3D framework of two-fold interpenetration assembled from trinuclear Cd(II) clusters bridged by bbi and L3? ligands. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
