Solid-phase reaction kinetics |
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Authors: | A Korobov |
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Institution: | 1. Kharkov University, P.O. Box 10313, 310023, Kharkov, Ukraine
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Abstract: | It is argued that, for the macroscopic parameters of conventional kinetic models to become meaningful, they may be and must be expressed in terms of elementary single-barrier processes. To accomplish this means to associate some (external) extensional measure with a single-barrier elementary act, remaining within the logic of the existing geometrical-probabilistic scheme. A manner of doing this involving the use of Dirichlet fragmentations is suggested. |
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