Highly chemoselective reduction of azides to amines by Fe(0) nanoparticles in water at room temperature |
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| Authors: | Subir Panja Debasish kundu Sabir Ahammed Brindaban C. Ranu |
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| Affiliation: | 1. Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700032, India |
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| Abstract: | A highly chemoselective reduction of aryl, heteroaryl, acyl and sulfonyl azides to the corresponding amines has been achieved by Fe(0) nanoparticles in water at room temperature in the absence of external hydride source. Several readily reducible functionalities including alkene, alkyne, S-S linkage, OTBDMS remain unaffected during reduction. |
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| Keywords: | Reduction Azide Fe(0) Nanoparticles Amines Chemoselectivity |
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