| N，N-二甲酰基二硫代氨基甲酸根金属配合物的研究 |
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| 引用本文： | 贺玲,史清芳,苟少华,方江邻,龚雁.N，N-二甲酰基二硫代氨基甲酸根金属配合物的研究[J].无机化学学报,1998,14(3):360-365. |
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| 作者姓名： | 贺玲 史清芳 苟少华 方江邻 龚雁 |
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| 作者单位： | 南京大学配位化学研究所配位化学国家重点实验室，南京 210093,南京大学配位化学研究所配位化学国家重点实验室，南京 210093,南京大学配位化学研究所配位化学国家重点实验室，南京 210093,南京大学配位化学研究所配位化学国家重点实验室，南京 210093,南京大学配位化学研究所配位化学国家重点实验室，南京 210093 |
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| 摘 要： | 本文首次报道了一系列N，N-二甲酰基二硫代氨基甲酸根为配体的过渡金属配合物，对它们进行了化学分析、光谱表征和磁性质研究。研究结果表明，在配合物中，配体二硫代氨基甲酸根一般为较弱的双齿配位。
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| 关 键 词： | 过渡金属配合物 N，N-二甲酰基二硫代氨基甲酸根配合物 1，1-二硫代氨基配体 |
STUDY ON THE TRANSITION METAL COMPLEXES OF N,N-DIFORMYLDITHIOCARBAMATE |
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| He Ling,Shi Qingfang,Gou Shaohu,Fang Jianglin and Gong Yan.STUDY ON THE TRANSITION METAL COMPLEXES OF N,N-DIFORMYLDITHIOCARBAMATE[J].Chinese Journal of Inorganic Chemistry,1998,14(3):360-365. |
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| Authors: | He Ling Shi Qingfang Gou Shaohu Fang Jianglin and Gong Yan |
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| Institution: | Coordination Chemistry Institute and State Key Laboratory of Coordination Chemsitry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute and State Key Laboratory of Coordination Chemsitry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute and State Key Laboratory of Coordination Chemsitry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute and State Key Laboratory of Coordination Chemsitry, Nanjing University, Nanjing 210093 and Coordination Chemistry Institute and State Key Laboratory of Coordination Chemsitry, Nanjing University, Nanjing 210093 |
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| Abstract: | A series of novel transition metal complexes of N,N-diformyldithiocarbamate, the first example of a dithiocarbamate with two N-substituted electron-withdrawing groups, have been prepared and characterized by chemical analysis as well as spectral and magnetic studies. A thorough inspection of the spectroscopic and magnetic data of these novel compounds demonstrates the weakly bidentate bonding mode of the carbodithioato ligand in the complexes. |
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| Keywords: | transition metal complex complexes of N N-diformyldithiocarbanate 1 1-carbodithioato ligand |
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