Synthesis and structures of novel enantiopure inherently chiral calix[4]arene-derived salphen ligands and their transition-metal complexes |
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Authors: | Zhen-Xiang Xu Zhi-Tang Huang |
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Affiliation: | a Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China b Graduate School, Chinese Academy of Sciences, Beijing 100049, China |
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Abstract: | Synthesis and structures of two pairs of novel enantiopure inherently chiral calix[4]arene-derived salphen ligands were described. Several Zn2+, Ni2+, and Cu2+ complexes of the chiral ligands were also prepared, and their structures were characterized by NMR, IR, CD, and HRMS spectra. |
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Keywords: | Inherently chiral calix[4]arene Salphen ligand Transition-metal complex Synthesis Structure |
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