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Synthesis and structures of novel enantiopure inherently chiral calix[4]arene-derived salphen ligands and their transition-metal complexes
Authors:Zhen-Xiang Xu  Zhi-Tang Huang
Affiliation:a Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b Graduate School, Chinese Academy of Sciences, Beijing 100049, China
Abstract:Synthesis and structures of two pairs of novel enantiopure inherently chiral calix[4]arene-derived salphen ligands were described. Several Zn2+, Ni2+, and Cu2+ complexes of the chiral ligands were also prepared, and their structures were characterized by NMR, IR, CD, and HRMS spectra.
Keywords:Inherently chiral calix[4]arene   Salphen ligand   Transition-metal complex   Synthesis   Structure
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