New insight into solid-state molecular dynamics: mechanochemical synthesis of azobenzene/triphenylphosphine palladacycles |
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Authors: | Cinčić Dominik Juribašić Marina Babić Darko Molčanov Krešimir Šket Primož Plavec Janez Ćurić Manda |
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Affiliation: | Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, HR-10000 Zagreb, Croatia. |
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Abstract: | Solid-state reactions of dicyclopalladated azobenzenes and triphenylphosphine lead to the thermodynamically favorable bridged complexes. It was demonstrated for the first time that very complex molecular dynamics involving a series of structural transformations is also feasible in the solid state. |
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