| 溴代酞菁铁配合物的光谱电化学性质研究 |
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| 引用本文： | 吴星,刘长庆,严鹏权,丁子庆.溴代酞菁铁配合物的光谱电化学性质研究[J].影像科学与光化学,1990,8(3):182-185. |
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| 作者姓名： | 吴星 刘长庆 严鹏权 丁子庆 |
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| 作者单位： | 扬州师范学院化学系, 扬州 225002 |
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| 摘 要： | 本文对μ-氧-四溴酞菁铁配合物(TBPcFe]2O)的电化学性质及光谱电化学性质进行了研究。结果表明,μ-氧-四溴酞菁铁在所研究的电压区问内经历了三个单电子氧化还原反应,其半波电势为0.06V,—0.75V及—1.33V(相对于甘汞电极),分别对应于Fe3+/Fe3=、Fe2+/Fe+及TBPc2-/TBPc3-电对的氧化还原反应。光谱电化学性质研究亦观察到相应酞菁配合物的特征光谱。
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| 关 键 词： | 四溴酞菁铁 光谱电化学 |
| 收稿时间： | 1988-09-21 |
SPECTRO-ELECTROCHEMICAL STUDY OF BROMOPHTHALOCYANINATO IRON |
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| WU XING,LIU CHANG-QING,YAN PENG-QUAN,DING ZI-QING.SPECTRO-ELECTROCHEMICAL STUDY OF BROMOPHTHALOCYANINATO IRON[J].Imaging Science and Photochemistry,1990,8(3):182-185. |
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| Authors: | WU XING LIU CHANG-QING YAN PENG-QUAN DING ZI-QING |
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| Institution: | Department of Chemistry, Yangzhou Teachers College, Yangzhou 225002, P. R. China |
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| Abstract: | Electrochemical and spectro-electrochemical properties of n-oxo-tetrabromophthalocyaninato iron (TBPcFe]2O) were studied.The experimental results showed that u-oxo-tetrabromoph-thalocyaninato iron undergoes three one-electron redox reactions,the half-wave potentials (E1/2) of which are 0.06V,-0.75V and -1.33V (Hg2Cl2/Hg reference),corresponding to Fe3+/ Fe2+,Fe2+/Fe+ and TBPc2-/TBPc3- respectively.The typical spectra of the corresponding; complexes were also observed in the spectro-electrochemical studies. |
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| Keywords: | tetrabromophthalocyaninato iron spectro-electrochemical method |
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