| Structure Studies on New Types of Macrocyclic Compounds Part V．Crystal Structure of Nickel（II） Complex of 5，12－Diphenyl－7，14－dimethyl－1，4，8，11－tetraazacyclotetradecane－N＇，N－diacetic Acid |
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| 作者姓名： | Lin Yu-Juan |
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| 作者单位： | Lin Yu-Juan(Fujian Institute of Research on the Structure of Matter，Academia Sinica，Fuzhou，350002)Chen Li-Qin;Ni Shi-Sheng;Xu Ji-De(Department of Chemistry，Anhui University，Hefei，230039) |
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| 摘 要： | ＳｔｒｕｃｔｕｒｅＳｔｕｄｉｅｓｏｎＮｅｗＴｙｐｅｓｏｆＭａｃｒｏｃｙｃｌｉｃＣｏｍｐｏｕｎｄｓＰａｒｔＶ．ＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆＮｉｃｋｅｌ（ＩＩ）Ｃｏｍｐｌｅｘｏｆ５，１２－Ｄｉｐｈｅｎｙｌ－７，１４－ｄｉｍｅｔｈｙｌ－１，４，８，...
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Structure Studies on New Types of Macrocyclic Compounds Part V.Crystal Structure of Nickel(II) Complex of 5, 12-Diphenyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradecane-N',N -diacetic Acid |
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| Lin Yu-Juan.Structure Studies on New Types of Macrocyclic Compounds Part V.Crystal Structure of Nickel(II) Complex of 5, 12-Diphenyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradecane-N',N -diacetic Acid[J].Chinese Journal of Structural Chemistry,1995(1). |
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| Authors: | Lin Yu-Juan |
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| Abstract: | Crystal structure of nickel(II) complex with a new 14 membered tetraazamacrocyclic ligand 5,12-diphenyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradecane-N',N-diacetic acid,NiN_4C_(10)(CH_2COO)_2(C_6H_5)_2]·2H_2O, M_r= 589. 38 is reported.It crystallizes in monoclinic P2_1/c space group with a=12.949(6),b=16.373(3),c=14.232(16),β=98.68(6)°,V=2982.9(7),Z=4,D_c=1.312 gcm-3,μ=6.953 cm-1,F(000)=1256.0.Finally,the structure was refined to R=0.080,R_w=0.065 for 2952 reflections.The central nickel ion of the complex forms an octahedron with four nitrogen atoms of the macrocycle and two oxygen atoms of the appended carboxylate groups.Two phenyl planes of the ligand are almost parallel to each other. |
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| Keywords: | crystal structure macrocyclic compound nickel complex |
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