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Conformations of isolated ampholytic dendrimers in solutions
Authors:Edward G. Timoshenko  Yuri A. Kuznetsov  George E. Simonov
Affiliation:1. Laboratory of Biomolecular Conformations, School of Chemistry and Chemical Biology, University College Dublin, Belfield, Dublin 4, Ireland;2. CSIC, Moscow State University, Moscow 119992, Russia
Abstract:
We study the conformations of isolated trifunctional ampholytic dendrimers in solutions. For the previously homo-dendrimer case studied in the literature, we discuss the issues of density profiles, the existence of a cavity, backfolding, bond stretching and scaling laws for the dendrimer size across the good-to-poor solvent transition. We then consider the effect of introducing monomer charges in the outermost generation opposite to those in the interior generations in an electrically neutral overall ampholytic co-dendrimer.
Keywords:Dendrimer   Polyampholyte   Conformation
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