Conformations of isolated ampholytic dendrimers in solutions |
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Authors: | Edward G. Timoshenko Yuri A. Kuznetsov George E. Simonov |
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Affiliation: | 1. Laboratory of Biomolecular Conformations, School of Chemistry and Chemical Biology, University College Dublin, Belfield, Dublin 4, Ireland;2. CSIC, Moscow State University, Moscow 119992, Russia |
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Abstract: | We study the conformations of isolated trifunctional ampholytic dendrimers in solutions. For the previously homo-dendrimer case studied in the literature, we discuss the issues of density profiles, the existence of a cavity, backfolding, bond stretching and scaling laws for the dendrimer size across the good-to-poor solvent transition. We then consider the effect of introducing monomer charges in the outermost generation opposite to those in the interior generations in an electrically neutral overall ampholytic co-dendrimer. |
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Keywords: | Dendrimer Polyampholyte Conformation |
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