Ion chromatography coupled with fluorescence/UV detector: A comprehensive review of its applications in pesticides and pharmaceutical drug analysis |
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| Authors: | Nadeem Muhammad Muhammad Zia-ul-Haq Amjad Ali Sumaira Naeem Azeem Intisar Dongxue Han Hairong Cui Yan Zhu Jia-Lun Zhong Abdul Rahman Binnian Wei |
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| Institution: | 1. Department of Environmental Engineering, Wuchang University of Technology, Wuhan, China;2. Department of Chemistry, Zhejiang University, Hangzhou 310028, China;3. State Key Laboratory of Metal Matrix, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, 200240, China;4. Research School of polymeric Materials, School of Material Science & Engineering, Jiangsu University, Zhenjiang, 202113, P.R. China;5. Department of Chemistry, University of Gujrat, Hafiz Hayat Campus Gujrat, Pakistan;6. Institute of Chemistry, University of the Punjab, Lahore, Pakistan;7. School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou, 510006, P.R. China;8. Guangzhou Institute of Advanced Technology, Chinese Academy of Sciences, Haibin Road no. 1121, Nansga District, Guangzhou 511458, China;9. Division of Cancer Prevention and Population Studies, Roswell Park Comprehensive Cancer Center, Buffalo, NY, USA |
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| Abstract: | Ion chromatography (IC) is a well-known technique for trace determination of inorganic ions and small organic acids. Recently, it has also appeared as a promising alternative to reverse phase chromatography for the determination of polar pesticides and pharmaceutical drugs in various sample matrices. Therefore, this study aims to provide a comprehensive overview of the application of IC coupled to fluorescence (FLD) or UV detector for the determination of pesticides and pharmaceutical drugs in samples from all walks of life. Apart from advantages and limitations, a short comparison of IC-FLD/UV with other techniques especially reverse-phase chromatography was drawn to envision future research efforts in this direction. Finally, several related areas such as IC hyphenation with different detectors (spectroscopic and spectrometer), miniaturization, automation, green chemistry, mobile phase, column, sample preparation, etc., were discussed to highlight its application for the determination of a wide range of analytes in the complex sample matrix. |
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| Keywords: | Ion chromatography Fluorescence UV Pesticides Pharmaceutical drugs |
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