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Acid-base properties of substituted tetraphenylmethylenediphosphine dioxides
Authors:E. I. Matrosov  K. Zh. Kulumbetova  L. I. Arkhipova  T. Ya. Medved'  M. I. Kabachnik
Affiliation:(1) Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR
Abstract:Conclusions Some tetraphenylmethylenediphosphine dioxides, substituted in the methylene bridge, were subjected to potentiometric titration in nitromethane with perchloric acid. The obtained values of the pKa basicity constants (CH3NO2) obey a linear relationship with the sgr* constants of the substituents.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 199–201, January, 1972.
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