Acid-base properties of substituted tetraphenylmethylenediphosphine dioxides |
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Authors: | E. I. Matrosov K. Zh. Kulumbetova L. I. Arkhipova T. Ya. Medved' M. I. Kabachnik |
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Affiliation: | (1) Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR |
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Abstract: | Conclusions Some tetraphenylmethylenediphosphine dioxides, substituted in the methylene bridge, were subjected to potentiometric titration in nitromethane with perchloric acid. The obtained values of the pKa basicity constants (CH3NO2) obey a linear relationship with the * constants of the substituents.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 199–201, January, 1972. |
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