Designing anti-migration furan-based plasticizers and their plasticization properties in poly (vinyl chloride) blends |
| |
| Institution: | 1. Institute of Chemical Industry of Forestry Products, CAF, Nanjing 210042, PR China;2. Jiangsu Province Biomass Energy and Materials Laboratory, Nanjing 210042, PR China;3. Institute of Forest New Technology, CAF, Beijing 100091, PR China;4. National Engineering Lab. for Biomass Chemical Utilization, Nanjing 210042, PR China;5. Key and Lab. on Forest Chemical Engineering, SFA, Nanjing 210042, PR China |
| |
| Abstract: | The use of bio-based plasticizers with low toxicity and good compatibility with polyvinyl chloride (PVC) has attracted more attention in the recent years. With bio-based 2, 5-furandicarboxylic acid (FDCA) and butyl oligo-glycol ethers as raw materials, three liquid furan-based plasticizers of di(butyl glycol) furan-2,5-dicarboxylate, di(butyldiglycol) furan-2,5-dicarboxylate and di(butyltriglycol) furan-2,5-dicarboxylate were synthesized by direct esterification. The chemical structure of three plasticizers was characterized with FTIR, 1H NMR and 13C NMR. From DMA measurement, the glass transition temperature (Tg) of the plasticized PVC was decreased gradually when furan-based plasticizers were added to PVC formulation from 30 up to 50 phr. Due to lots of ether bonds in furan-based plasticizers, they expressed over two-fold lower migration in organic solvent compared with the traditional plasticizer diethylhexyl phthalate (DEHP). Through the characterization of elongation at break, hardness and thermal stability, furan-based plasticizers presented the same plasticization properties as DEHP, and had potential industrial application prospects. |
| |
| Keywords: | Ether ester plasticizer Anti-migration |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
