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In situ generation of H2Se and hydrothermal synthesis of new polynuclear rhenium carbonyl polyselenides |
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| Authors: | Maxim N. Sokolov Pavel A. Abramov Eugenia V. Peresypkina Alexander V. Virovets Vladimir P. Fedin |
| Affiliation: | 1. Nikolayev Institute of Inorganic Chemistry, Prospekt Lavrentyeva 3, 630090 Novosibirsk, Russia;2. Novosibirsk State University, ul. Pirogova 2, 630090 Novosibirsk, Russia |
| Abstract: | Two new polyselenide-bridged rhenium carbonyl complexes, [Re5(CO)18(Se2)3]− and [Re4(CO)14(Se2)(Se5)], were obtained by hydrothermal reaction of [Re(CO)5Cl] with in situ generated H2Se and have been characterized by X-ray diffraction. |
| Keywords: | Rhenium Selenide Self-assembly Hydrothermal synthesis X-ray diffraction |
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