|
|||||
|
|
| 双核配合物[Cu2(L-Asp)(phen)3(NO3)](NO3)·4H2O的合成及晶体结构 | |
| 引用本文： | 马录芳,梁福沛,覃海错,胡瑞祥,张漫波,郁开北. 双核配合物[Cu2(L-Asp)(phen)3(NO3)](NO3)·4H2O的合成及晶体结构[J]. 无机化学学报, 2004, 20(12): 1429-1432 |
| 作者姓名： | 马录芳 梁福沛 覃海错 胡瑞祥 张漫波 郁开北 |
| 作者单位： | 1. 广西师范大学化学化工学院,桂林,541004;洛阳师范学院化学系,洛阳,471022 2. 广西师范大学化学化工学院,桂林,541004 3. 中科院成都有机所分析测试中心,成都,610041 |
| 基金项目： | 广西自然科学基金资助项目(No.9912044) |
| 摘 要： | The new complex [Cu2(L-Asp)(phen)3(NO3)](NO3)·4H2O (L-Asp=L-aspartic acid and phen=1,10-phenanthroline) has been synthesized and its crystal structure has been determined. The complex crystallizes in the monoclinic with space group P21/c, The cell parameters are: a=1.261 3(2) nm, b=1.500 8(4) nm, c=2.230 7(4) nm, β=99.55(1)°, and V=4.164 1(16) nm3，Dc=1.587 g·cm-3. The complex contains two six-coordinated copper ions, and these two copper ions are connected together by L-aspartate to give rise to a binuclear structure. Hydrogen bonds and π-π stacking interactions are observed in the complex. CCDC: 249250. |
| 关 键 词： | 天冬氨酸 1，10-邻菲咯啉 铜(Ⅱ)配合物 晶体结构 |
| 修稿时间： | 2004-03-15 |
Synthesis and Crystal Structure of Binuclear Complex [Cu2(L-Asp)(phen)3(NO3)](NO3)·4H2O |
|
| MA Lu-Fang,LIANG Fu-Pei,QIN Hai-Cuo,HU Rui-Xiang,ZHANG Man-Bo and YU Kai-Bei. Synthesis and Crystal Structure of Binuclear Complex [Cu2(L-Asp)(phen)3(NO3)](NO3)·4H2O[J]. Chinese Journal of Inorganic Chemistry, 2004, 20(12): 1429-1432 | |
| Authors: | MA Lu-Fang LIANG Fu-Pei QIN Hai-Cuo HU Rui-Xiang ZHANG Man-Bo YU Kai-Bei |
| Affiliation: | School of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004;Department of Chemistry, Luoyang Teacher's College, Luoyang 471022,School of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004,School of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004,School of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004,School of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004 and Chengdu Center of Analysis and Measurement, Academia science, Chengdu 610041 |
| Abstract: | |
| Keywords: | L-aspartic acid 1 10-phenanthroline copper(II) complex c rystal structure |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |
| 点击此处可从《无机化学学报》浏览原始摘要信息 | |
| 点击此处可从《无机化学学报》下载全文 | |