| 一个基于5-(3-氨基-吡啶-4-基)-间苯二羧酸和桨轮状[Cu2(COO)4]簇的rtl-金属有机骨架材料的合成及其CO2选择性吸附性质 |
| |
| 引用本文： | 孟柳丽,程宏涛,薛东旭,王倩,白俊峰.一个基于5-(3-氨基-吡啶-4-基)-间苯二羧酸和桨轮状[Cu2(COO)4]簇的rtl-金属有机骨架材料的合成及其CO2选择性吸附性质[J].无机化学学报,2020,36(6):1098-1104. |
| |
| 作者姓名： | 孟柳丽 程宏涛 薛东旭 王倩 白俊峰 |
| |
| 作者单位： | 陕西师范大学化学化工学院, 应用表面与胶体化学教育部重点实验室, 西安 710062;1 陕西师范大学化学化工学院, 应用表面与胶体化学教育部重点实验室, 西安 710062;陕西师范大学化学化工学院, 应用表面与胶体化学教育部重点实验室, 西安 710062;1 陕西师范大学化学化工学院, 应用表面与胶体化学教育部重点实验室, 西安 710062;陕西师范大学化学化工学院, 应用表面与胶体化学教育部重点实验室, 西安 710062;南京大学化学化工学院, 配位化学国家重点实验室, 南京 210023 |
| |
| 基金项目： | 国家自然科学基金（No.21771121）和中央高校基金（No.GK201903040）资助项目。 |
| |
| 摘 要： | 利用新配体5-（3-氨基-吡啶-4-基）-间苯二羧酸（NH2-H2L1），我们成功设计、合成了一例氨基功能化的柱-层型rtl-MOF，SNNU-Bai65。与原型MOF（SYSU）对比，极性官能团氨基对孔表面的功能性修饰和对孔道的分割使得SNNU-Bai65经活化后展现出更好的CO2/N2和CO2/CH4的选择性CO2吸附性能。
|
| 关 键 词： | 氨基功能化rtl-MOF 选择性CO2吸附 |
| 收稿时间： | 2020/1/10 0:00:00 |
| 修稿时间： | 2020/3/26 0:00:00 |
Synthesis and Selective CO2 Adsorption of a rtl-MOF Based upon 5-(3-Amino-pyridin-4-yl)-isophthalic Acid and [Cu2(COO)4]-Paddlewheel Unit |
| |
| MENG Liu-Li,CHENG Hong-Tao,XUE Dong-Xu,WANG Qian,BAI Jun-Feng.Synthesis and Selective CO2 Adsorption of a rtl-MOF Based upon 5-(3-Amino-pyridin-4-yl)-isophthalic Acid and [Cu2(COO)4]-Paddlewheel Unit[J].Chinese Journal of Inorganic Chemistry,2020,36(6):1098-1104. |
| |
| Authors: | MENG Liu-Li CHENG Hong-Tao XUE Dong-Xu WANG Qian BAI Jun-Feng |
| |
| Institution: | Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an 710062, China;1 Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an 710062, China;Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an 710062, China; 1 Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an 710062, China;Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an 710062, China;State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China |
| |
| Abstract: | Based upon a new ligand of 5-(3-amino-pyridin-4-yl)-isophthalic acid (NH2-H2L1), the NH2-functionalized pillar-layer rtl-MOF, SNNU-Bai65, has been successfully designed and synthesized. With the polar amino group decorating the pore surface and partitioning the pore channel, activated SNNU-Bai65 exhibits more highly selective CO2 adsorption over N2 and CH4 than the parent MOF, SYSU. |
| |
| Keywords: | amino-functionalization rtl-MOF selective CO2 adsorption |
|
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|
