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Time-resolved ESR and endor during the photolysis of ω,ω-dimethoxy-ω-phenyl-acetophenone
Authors:Petra Jaegermann   Friedhelm Lendzian    nther Rist  Klaus Mobius
Affiliation:

a Institute for Molecular Physics, Free University of Berlin, D-1000 Berlin 33, West Germany

b Ciba-Geigy Ltd., R-1062.302, CH-4002 Basel, Switzerland

Abstract:
The ketone ω,ω-dimethoxy-ω-phenyl-acetophenone (DMPA) is an efficient initiator in UV-curing polymerization processes started by photochemically generated radicals. The short-lived radical intermediates created during the photolysis of DMPA have been investigated by time-resolved ESR and ENDOR spectroscopy taking advantage of a strong CIDEP effect.
Keywords:
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