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Solvent effects in ligand substitutions of square planar complexes
Authors:K. M. Ibne-Rasa  J. O. Edwards  J. L. Rogers
Affiliation:(1) Department of Chemistry, Brown University, 02912 Providence, Rhode Island
Abstract:Data on solvent effects in ligand substitution in square planar complexes are reviewed. In view of the fact that solvent effects for reactions of the planar complexes are quite different from those observed for saturated carbon substrates, it is felt that previous explanations for protic-dipolar aprotic solvent effects may have to be reconsidered.
Keywords:Transition-metal complex ions  square planar complexes  nucleophilic displacement  solution kinetics
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