Complex Formation on the Surface of Tungsten on Its Chlorination in DMF Medium |
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| Authors: | E. N. Trifonova A. A. Mukhanova A. I. Stepanov N. F. Drobot V. A. Krenev D. V. Drobot |
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| Affiliation: | (1) Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia;(2) Lomonosov Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571, Russia |
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| Abstract: | ![]()
IR spectroscopy and chromato-mass spectrometry were used to investigate the surface layer of tungsten after its chlorination in a medium of DMF containing water. The mechanism of this process is similar to that of the previously described chlorination of rhenium and molybdenum and is determined by the participation of a complex formed in the DMF-H2O-Cl2 system.__________Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 6, 2005, pp. 436–440.Original Russian Text Copyright © 2005 by Trifonova, Mukhanova, Stepanov, N. Drobot, Krenev, D. Drobot. |
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