ESR spectra of endohedral metallofullerene Ce@C82 radical anions in dimethylformamide and pyridine |
| |
| Authors: | Solodovnikov S. P. Lebedkin S. F. |
| |
| Affiliation: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation;(2) Research Center of Karlsruhe, Institute of Solid State Nuclear Physics, D-76021 Karlsruhe, Germany |
| |
| Abstract: | Endohedral metallofullerene Ce@C82 dissolved in dimethylformamide or pyridine is reduced to the radical anion. Analysis of hyperfine coupling with the topologically different 13C nuclei indicates the electronic structure with bivalent cerium and the paramagnetic carbon framework Ce2+@C82·3–. The ESR spectra of the radical anions of the functionalized Ce@C82 derivatives are detected. |
| |
| Keywords: | endohedral metallofullerenes ESR spectroscopy reduction nitrogen-containing solvents |
| 本文献已被 SpringerLink 等数据库收录！ |
