A new synthesis ofE- andZ(-)(1R,3S)-2,2-dimethyl-3-(3,3,3-trifluoro-2-chloropropen-1-yl)cyclopropanecarboxylic acids from (+)-3-carene |
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| Authors: | F Z Makaev F Z Galin G A Tolstikov |
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| Institution: | (1) Institute of Chemistry, Academy of Sciences of Moldova, 3 ul. Akademicheskaya, 277028 Kishinev, Moldova;(2) Institute of Organic Chemistry, Ural Branch of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation |
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| Abstract: | A new synthesis ofE- andZ(-)(1R,3S)-2,2-dimethyl-3-(3,3,3-trifluoro-2-chloropropen1-yl)cyclopropanecarboxylic acids from (+)-3-carene in 21 % total yield was carried out.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 517–518, March, 1995. |
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| Keywords: | a mixture ofE- andZ(-)(1R 3S)-2 2-dimethyl-3-(3 3 3-trifluoro-2-chloropropen-1-yl)cyclopropanecarboxylic acids (1R 3S)-2 2-dimethyl-3-(2-oxopropyl)cyclopropanecarboxylic acid mixed anhydride of acetic and (1R 3S)-2 2-dimethyl-3-formylcyclopropanecarboxylic acids ozonolysis |
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