The crystal and molecular structure of ammonium-bis(malonato) oxovanadium(IV) dihydrate |
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| Authors: | O. E. Piro E. J. Baran |
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| Affiliation: | (1) Departamento de Física, Facultad de Ciencias Exactas, Universidad Nacional de La Plata and Programa Profimo(Conicet), C.C. 67, 1900 La Plata, Argentina;(2) Cequinor (Conicet), Universidad Nacional de La Plata, C.C. 962, 1900 La Plata, Argentina |
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| Abstract: | ![]()
The title compound, (NH4)2[VO(C3H2O4)2]·2H2O, crystallizes in the monoclinic space group P21/n, with a=7.1889(7), b=19.254(2), c=9.879(2) Å, β=108.19(1)o, and Z=4. The VO2+ cation is five-fold coordinated with two malonate anions acting as bidentate ligands and a water molecule. Infrared and Raman spectra are also reported to attain a wider insight into the compound characteristics. |
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| Keywords: | Bis(malonato)oxovanadium(IV) crystal structure IR and Raman spectra |
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