Induced decomposition of di(tert-butyl)trioxide |
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| Authors: | S. L. Khursan A. F. Khalizov V. V. Shereshovets |
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| Affiliation: | (1) Bashkortostan State University, 32 ul. Frunze, 450074 Ufa, Russian Federation;(2) Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation |
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| Abstract: | Thermal decomposition of di(tert-butyl)trioxide (ButOOOBut) in a wide range of concentrations was studied by visible and IR chemiluminescence. Induced decomposition of ButOOOBut caused by its reaction with the peroxy radicals formed in the solvent (CH2Cl2) was found and investigated. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 924–927, May, 1997. |
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| Keywords: | trioxides thermal decomposition mechanism di(tert-butyl)trioxide induced decomposition chemiluminescence |
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