Synthese und Struktur gemischt‐substituierter Dialane Al2X2{Si(SiMe3)3}2 · 2 THF (X = Cl,Br) |
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| Authors: | Christoph Klemp,Christoph Ü ffing,Elke Baum,Hansgeorg Schnö ckel |
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| Abstract: | Synthesis and Structure of two Mixed Substituted Dialanes Al2X2{Si(SiMe3)3}2 · 2 THF (X = Cl, Br) The syntheses of tris(trimethylsilyl)silyl (hypersilyl) and halide substituted dialanes Al2X2{Si(SiMe3)3}2 · 2 THF (X = Cl, Br) are presented. The results of the X‐ray diffraction experiments are presented and discussed in comparison to the AlIII compounds AlBr2Si(SiMe3)3 · THF and AlBr3 · OPh2. |
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| Keywords: | Aluminum Subvalent compounds Crystal structure Metal‐metal interactions |
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