Novel aggregation of [Ni(thiolato)2(amine)2]-type square planes assisted by silver(I) ions |
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| Authors: | Konno Takumi Usami Masafumi Hirotsu Masakazu Yoshimura Takashi Kawamoto Tatsuya |
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| Institution: | Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. konno@ch.wani.osaka-u.ac.jp. |
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| Abstract: | Treatment of Ni(L)]L =((-)SCH(2)CH(2)NHdouble bond, length as m-dash]C(CH(3))-)(2)] with Ag(+) in water gave a pinwheel-like S-bridged Ni(II)(3)Ag(I)(2) structure in Ag(2)Ni(L)](3)](2+), which further reacted with Ni(L)] to produce a Ni(II)(4)Ag(I)(2) structure in Ag(2)Ni(L)](4)](2+) and a Ni(II)(7)Ag(I)(4) structure in Ag(4)Ni(L)](7)](4+). |
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