Cyanide-bridged W(V)-Co(II) double-zigzag chain based on an octacoordinated W precursor: metamagnetism and spin canting |
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| Authors: | Yoon Jung Hee Lim Jeong Hak Choi Seok Woo Kim Hyoung Chan Hong Chang Seop |
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| Affiliation: | Department of Chemistry and Center for Electro- and Photo-Responsive Molecules, Korea University, Seoul 136-701, Korea. |
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| Abstract: | ![]()
A cyanide-bridged W-Co bimetallic complex (1) with a double-zigzag chain structure was characterized in terms of structure and magnetism. Compound 1 exhibits metamagnetism and spin canting induced by the presence of anisotropic CoII ions and noncovalent interactions. |
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