SF and SC Activation of SF6 and SF5 Derivatives at Rhodium: Conversion of SF6 into H2S |
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| Authors: | Lada Zámostná Prof Dr Thomas Braun Dr Beatrice Braun |
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| Institution: | Department of Chemistry, Humboldt‐Universit?t zu Berlin, Brook‐Taylor‐Strasse 2, 12489 Berlin (Germany) |
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| Abstract: | The degradation of SF6 and SF5 organyls by S? F and S? C bond‐activation reactions at {Rh(μ‐H)(dippp)}2] under mild conditions is reported. Fluorido and thiolato species were identified as products or intermediates, and were characterized by X‐ray diffraction analysis and multinuclear NMR spectroscopy. An unprecedented cyclic process for the conversion of the potent greenhouse gas SF6 into H2S was developed. |
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| Keywords: | fluorido complexes pentafluorosulfanyl compounds rhodium S F activation sulfur hexafluoride |
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