(NH3CH2CH2NH3)B6O9(OH)2: Synthesis and crystal structure of a novel layered borate templated by ethylenediamine |
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| Authors: | Min Li Jiazhong Chang Hengzhen Shi |
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| Institution: | a Department of Chemistry, Zhoukou Normal University, Zhoukou 466001, Henan Province, PR China
b Analytical Testing Centre, Zhoukou Normal University, Zhoukou 466001, Henan Province, PR China |
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| Abstract: | A novel intercalated borate compound (NH3CH2CH2NH3)B6O9(OH)2, has been solvothermally synthesized, and structurally characterized by single crystal X-ray diffraction. Compound crystallizes in the monoclinic, space group P2(1)/c,  ,  ,  , β=93.32(3)°,  , Z=4. Its oxoborate structure is built up from 1-D polyborate chains with 3, 11-membered boron rings bonded diamine molecules through electrostatic attraction and hydrogen bond interactions to construct 2-D layered compound. Other characterizations by IR, element analysis, thermal analysis and specific surface area are also discussed. |
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| Keywords: | Solvothermal synthesis Crystal structure Intercalated borate |
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