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电位溶出法测定铅和镉
引用本文:郭小群.电位溶出法测定铅和镉[J].化学研究与应用,2007,19(5):571-573.
作者姓名:郭小群
作者单位:四川理工学院化学系,四川,自贡,643000
基金项目:四川省教育厅重点专项(2005D007)资助,四川理工学院教改项目资助(J-0619)
摘    要:重金属铅和镉元素在环境中普遍存在并可长期蓄积,是不可降解的环境污染物,常危害人体健康.建立快速准确的测定方法具有实际意义1].

关 键 词:聚苯胺电极  电位溶出法      
文章编号:1004-1656(2007)05-0571-03
收稿时间:2006-11-07
修稿时间:2007-03-18

Determination of Pb and Cd by stripping voltammetry
GUO Xiao-qun.Determination of Pb and Cd by stripping voltammetry[J].Chemical Research and Application,2007,19(5):571-573.
Authors:GUO Xiao-qun
Institution:Department of Chemistry, Sichuan University of Science Engineering, Zigong 643000, China
Abstract:A method for the determination of Pb and Cd with trace level by stripping voltammetry on the polyaniline electrode modified with Bi particles was investigated. Various kinds of experimental conditions for the determination of Pb and the deposition of Bi particles on the electrode were discussed. The results showed that a stripping potential peak with high sensitivity about Pb or Cd could be achieved, which was similar to that of the modified electrode. Furthermore, the electrode has shown a high stability and a work curve with a fairly good linearity. Meanwhile, a satisfing analytical result of the Pb concentration with trace level in tap water was achieved.
Keywords:Polyaniline electrode  stripping voltammetric measurement  Bi microparticle  Pb  Cd
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