| 亚相金属离子与两亲配体LB膜相互作用的研究 |
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| 引用本文： | 欧阳健明,邰子厚,唐雯霞. 亚相金属离子与两亲配体LB膜相互作用的研究[J]. 物理化学学报, 1998, 14(1): 84-87. DOI: 10.3866/PKU.WHXB19980116 |
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| 作者姓名： | 欧阳健明 邰子厚 唐雯霞 |
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| 作者单位： | Department of Chemistry,Jinan University,Guangzhou 510632,State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing 210093 |
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| 基金项目： | 国家自然科学基金，广东省自然科学基金，南京大学配位化学研究所国家重点实验室基金 |
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| 摘 要： |
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| 关 键 词： | XPS LB膜 金属离子 界面 2-十六胺基酰基-8-羟基喹啉 |
| 收稿时间： | 1997-03-11 |
| 修稿时间： | 1997-05-19 |
XPS Study of LB Films of Amphiphilic Ligand on Surface of the Subphase Containing Metal lons |
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| Ouyang Jian-Ming,Tai Zi-Hou,Tang Wen-Xia. XPS Study of LB Films of Amphiphilic Ligand on Surface of the Subphase Containing Metal lons[J]. Acta Physico-Chimica Sinica, 1998, 14(1): 84-87. DOI: 10.3866/PKU.WHXB19980116 |
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| Authors: | Ouyang Jian-Ming Tai Zi-Hou Tang Wen-Xia |
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| Affiliation: | Department of Chemistry,Jinan University,Guangzhou 510632|State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing 210093 |
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| Abstract: | The complex formation of 2-hexadecylcarbamoyl-8-hydroxyquinoline(HHQ) monolayers at the air/water interface by reaction with metal ions from the subphase was investigated using X-ray photoelectron spectroscopy. The formation of HHQ-metal complexes leads to the appearance of new peaks assigned to the metal ions. The information on stoichimoetry provided by XPS indicated that a metal ion is coordinated by two HHQ molecules for La3+ and Cd2+ ions, but by one HHQ molecule for Mn2+ and Ni2+ ions. |
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| Keywords: | X-ray photoelectron spectroscopy Langmuir-Blodgett (LB) Films Metal ion Interface 2-hexadecylcarbamoyl-8-hydroxyquinoline |
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