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PS-b-PMMA对PVC/SBS共混体系界面结构的影响
引用本文:李春刚,张邦华,宋谋道,周庆业.PS-b-PMMA对PVC/SBS共混体系界面结构的影响[J].物理化学学报,1998,14(2):188-192.
作者姓名:李春刚  张邦华  宋谋道  周庆业
作者单位:The State Key Laboratory of Polymer Materials Engineering,Chengdu 610065,The State Key Laboratory of Funetional Polymer Materials for Adsorption and Separation,Institute of Polymer Chemistry,Nankai University,Tianjin 300071
摘    要:在两种不相容的聚合物组成的共混体系中加入增容剂,可以显著提高共混体系的力学性能.目前的理论解释是嵌段共聚物在不相容的聚合物间形成界面层,通过降低组分间的界面张力、增强界面粘接力达到增容目的[‘-‘1.但是这一假设缺乏直接的实验证据.本文利用透射电子显微镜,

关 键 词:嵌段共聚物  共混体系  增溶剂  界面结构  
收稿时间:1997-06-05
修稿时间:1997-10-04

Influence of PS-b-PMMA on the Interface Structure of PVC/SBS Blends
Li Chungang, Zhang Banghua, Song Moudao, Zhou Qingye.Influence of PS-b-PMMA on the Interface Structure of PVC/SBS Blends[J].Acta Physico-Chimica Sinica,1998,14(2):188-192.
Authors:Li Chungang  Zhang Banghua  Song Moudao  Zhou Qingye
Institution:The State Key Laboratory of Polymer Materials Engineering,Chengdu 610065|The State Key Laboratory of Funetional Polymer Materials for Adsorption and Separation,Institute of Polymer Chemistry,Nankai University,Tianjin 300071
Abstract:The influence of poly(styrene-b-methyl methacrylate) on the interface of PVC/SBSblends is studied by TEM and DMA, When only two pwrcent of PS-b-PMMA is added to PVC/SBS(100/15) blends ,the thickness of the interface get thickened obviously, The molecular weight and the composition of PMMA blocks and PS bolcks have important influence on theinterface of PVC/SBS blends.
Keywords:Block copolymer  Blends  Compatibilizer  Interface
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