Institution: | 1. Department of Mathematics and Natural Sciences, Gulf University for Science and Technology, 32093 Hawally>2. , Kuwait
Functional Materials Group – CAMB, Gulf University for Science and Technology, 40006 West Mishref, Kuwait;3. Petroleum Research Center, Kuwait Institute for Scientific Research, 70051 Safat, Kuwait;4. Kuwait Oil Company, 60000 Ahmadi<5. , Kuwait |
Abstract: | We report the synthesis, characterization, and photophysical properties of novel metal oxide nanoparticles (NPs) coated with specially designed fluorescein substituents which are capped with electron-withdrawing groups. The fluorescein-coated nanoparticles were synthesized in excellent yields, and their structures were confirmed using various advanced spectroscopic, instrumental, and surface analysis techniques, revealing the formation of the target functionalized nanoparticles (FNPs) which show superior chemical and thermal stabilities. In addition, the photophysical properties of the FNPs were examined using UV-visible absorption and fluorescence spectroscopy. These latter techniques disclosed aggregation-induced emission (AIE) properties for most of the target FNPs, namely those which are soluble in common organic solvents at selective concentration ranges of water fractions in the solvent mixture. |