N-aminorhodamne complexes of palladium(II), palladium(IV) and platinum(II) |
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| Authors: | A. C. Fabretti G. C. Franchini Giorgio Peyronel |
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| Affiliation: | (1) Istituto di Chimica Generale e Inorganica, University of Modena, 41100 Modena, Italy |
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| Abstract: | Summary TheN-aminorhodanine (L) complexes: PdLX, (X = Br or I), ML1.5Cl2 (M = Pd or Pt), PtL2X2 (X = Br, I or ClO4), PdL3(ClO4)2, PdL1.5Cl4 and PdL3(ClO4)4 have been prepared and investigated. The ligand is bonded to the metal ion through the aminic nitrogen atom as monodentate or through this atom and the thiocarbonylic sulphur atom when it acts as chelating or bridging ligand. The carbonylic oxygen atom is never coordinated. |
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