| 手性膦氮配体的合成及其过渡金属配合物对不对称氢转移反应的催化作用 |
| |
| 引用本文： | 何炜,姜茹,刘鹏,柳文敏,张生勇. 手性膦氮配体的合成及其过渡金属配合物对不对称氢转移反应的催化作用[J]. 应用化学, 2006, 23(11): 1195-0 |
| |
| 作者姓名： | 何炜 姜茹 刘鹏 柳文敏 张生勇 |
| |
| 作者单位： | 第四军医大学 |
| |
| 基金项目： | 国家自然科学基金;陕西省自然科学基金 |
| |
| 摘 要： | 金鸡纳生物碱;手性膦氮配体;不对称氢转移反应
|
| 关 键 词： | 金鸡纳生物碱 手性膦氮配体 不对称氢转移反应 |
| 文章编号： | 1000-0518（2006）11-1195-05 |
| 收稿时间： | 2005-11-22 |
| 修稿时间： | 2006-03-04 |
Synthesis of Chiral P,N-Ligands and Catalytic Application of their Transition Metal Complexes in Asymmetric Transfer Hydrogenation |
| |
| HE Wei,JIANG Ru,LIU Peng,LIU Wen-Min,Zhang Sheng-Yong. Synthesis of Chiral P,N-Ligands and Catalytic Application of their Transition Metal Complexes in Asymmetric Transfer Hydrogenation[J]. Chinese Journal of Applied Chemistry, 2006, 23(11): 1195-0 |
| |
| Authors: | HE Wei JIANG Ru LIU Peng LIU Wen-Min Zhang Sheng-Yong |
| |
| Abstract: | Four chiral P,N-ligands were synthesized in high yields from natural cinchona alkaloids under mild conditions.Their Ir,Rh,Ru complexes were applied as asymmetric catalysts in asymmetric transfer hydroge-(nation).The results show that high chemical yields(up to 95%) and moderate ee could be obtained(up to 75.3%). |
| |
| Keywords: | cinchona alkaloid chiral P N-ligand asymmetric transfer hydrogenation |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《应用化学》浏览原始摘要信息 |
|
点击此处可从《应用化学》下载全文 |
