Decomposition of 1,1-dichloroethene on Pd(111) |
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| Authors: | Hunka Deborah E Herman Daniel C Lormand Kara D Jaramillo Donna M Land Donald P |
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| Institution: | Department of Chemistry, University of California, Davis, California 95616, USA. |
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| Abstract: | The decomposition of 1,1-dichloroethene on Pd(111) is investigated using conventional thermal desorption, laser-induced thermal desorption (LITD), and FT reflection absorption infrared spectroscopy (FT-RAIRS). The decomposition mechanism produces at least three hydrocarbon surface intermediates, including ethylidyne. Thermal desorption results differ between high and low coverages because of relative surface concentrations of Cl and H in combination with kinetic effects. |
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