Diazabutadienes as σ,π-bridging ligands in binuclear molybdenum carbonyl complexes containing molybdenummolybdenum double bonds |
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| Authors: | L.H. Staal A. Oskam K. Vrieze |
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| Affiliation: | Anorganisch Chemisch Laboratorium, J.H. van ''t Hoff Instituut, University of Amsterdam, Nieuwe Achtergracht 166, Amsterdam The Netherlands |
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| Abstract: | Reduction of Mo(CO)4 DAB (DAB = diazabutadiene) followed by oxidation with Mn(CO)3BrDAB or HCl gives a small yield (15 to 25%) of complexes of the type Mo2(CO)6(DAB)2, in which the two DAB ligands bridge a molybdenummolybdenum double bond and act as σ,π-donors. |
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| Keywords: | To whom correspondence should be addressed. |
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