The structure of (C5H52W(CO)2 a compound containing a bent trihapto-cyclopentadienyl ligand |
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| Authors: | Gottfried Huttner Hans H. Brintzinger Larry G. Bell Peter Friedrich Vera Bejenke Dietmar Neugebauer |
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| Affiliation: | Fachbereich Chemie, Universität Konstanz, D-7750 Konstanz B.R.D.;Anorganisch-Chemisches Laboratorium der Technischen Universität München, D-8000 München B.R.D. |
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| Abstract: | ![]()
The crystal and molecular structure of the complex (C5H5)2W(CO)2 has been determined by X-ray analysis R1 = 0.063). The structure contains a trihapto-cyclopentadienyl ligand, bent along its 1,3-axis by 20°. By this unusual structure, a 20-electron valence configuration of the central metal is avoided. |
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