| 超微盘电极上阶梯扫描伏安法可逆波理论 |
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| 引用本文： | 于俊生 张祖训. 超微盘电极上阶梯扫描伏安法可逆波理论[J]. 高等学校化学学报, 1992, 13(10): 1229-1232 |
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| 作者姓名： | 于俊生 张祖训 |
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| 作者单位： | 南京大学化学系, 南京, 210008 |
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| 基金项目： | 高等学校博士学科点专项科研基金 |
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| 摘 要： | 本文报道超微盘电极上阶梯扫描伏安法可逆波理论,对电流-电位曲线的性质进行了讨论.利用K4Fe(CN)6·KCl体系进行了验证,实验结果与理论相符.
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| 关 键 词： | 阶梯扫描伏安法 超微盘电极 可逆波理论 |
| 收稿时间： | 1991-10-15 |
The Theory of Reversible Wave at Ultramicrodisk Electrodes in Staircase Sweep Voltammetry |
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| YU Jun-Sheng,ZHANG Zu-Xun. The Theory of Reversible Wave at Ultramicrodisk Electrodes in Staircase Sweep Voltammetry[J]. Chemical Research In Chinese Universities, 1992, 13(10): 1229-1232 |
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| Authors: | YU Jun-Sheng ZHANG Zu-Xun |
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| Affiliation: | Department of Chemistry, Nanjing University, Nanjing, 210008 |
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| Abstract: | An equation is derived for the current response of a reversible electron transfer reaction for staircase sweep voltammetry at uhramicrodisk electrodes and verified experimentally.Characters of its current potential curves are discussed.Experimental results for oxidation of K4Fe(CN)6 at uhramicrodisk platinum electrodes agree well with the theory. |
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| Keywords: | Staircase sweep voltammetry Ultramicrodisk electrode Theory of reversible wave |
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