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Syntheses and Characterizations of (4-NH2C6H4S)4Sn and [(4-NH2C6H4S)2(4-NH3C6H4S)2Sn]Cl2
Authors:WANG Long-Sheng  ZHANG Jian-Jun  DU Wen-Xin  HU Sheng-Min  FU Rui-Biao  Xia Sheng-Qing  WU Xin-Tao  XIANG Sheng-Chang  LI Ya-min  FU Zhi-yong
Institution:State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Abstract:Two mononuclear tin(IV) corn-plcxes, (4-NH2C6H4S)4Sn 1 and (4-NH2C6H4S)2(4-NH3C6H4S)2Sn]Cl2 2, have been synthesized and charac-terized by X-ray structure analysis. The Sn4 ion in 1 is four-coordinated to form a highly distorted tetrahedral configuration, while that in 2 adopts a slightly distorted tetrahedron.
Keywords:tin-sulphur complex  4-aminobenzenethiol  hydrogen bond  weak interaction
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