Study of cesium phospho(vanado)molybdates active in the oxidative dehydrogenation of cyclohexane期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Study of cesium phospho(vanado)molybdates active in the oxidative dehydrogenation of cyclohexane

Authors:	Sma?n Hocine Chérifa Rabia Mohammed M Bettahar and Michel Fournier

Institution:	(1) Laboratoire de Chimie du Gaz Naturel, Institut de Chimie, USTHB, BP32, El-Alia, 16111, Algérie;(2) Laboratoire de Catalyse Hétérogène, UMR CNRS 7565, Université Henri, Poincarré-Nancy 1, BP 239, 54506 Vandoeuvre-lès-Nancy, Cedex, France;(3) Laboratoire de Catalyse Hétérogène et Homogène, URA CNRS N°402 Batiment C3, 59655 Villeneuve d'Ascq Cedex, France

Abstract:	Cs₂.₅M_0.08H_0.26PMo₁₂O₄₀and Cs₂.₅M_0.08H_1.26PMo₁₁VO₄₀(M: Ni, Fe) heteopolyanions were selectively prepared, characterized by IR, Raman, ³¹P NMR, XPS and XRD and tested in the ODH of cyclohexane. The salt structure, and reaction mechanism and kinetics are discussed. This revised version was published online in June 2006 with corrections to the Cover Date.

Keywords:	ODH cyclohexane Heteropolyanions
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