Stereoselective synthesis of L-oliose trisaccharide via iterative alkynol cycloisomerization and acid-catalyzed glycosylation |
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| Authors: | McDonald Frank E Wu Minglang |
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| Affiliation: | Department of Chemistry, Emory University, 1515 Pierce Drive, Atlanta, Georgia 30322, USA. fmcdona@emory.edu |
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| Abstract: | ![]()
[formula: see text] The synthesis of an all-alpha L-oliose diastereomer of digitoxin provides valuable insights into the generality and protective-group dependence of acid-catalyzed glycosylations of glycals to 2-deoxycarbohydrates. |
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