Anomalous hydroalumination of methyl nopol ether with a LiAlH4-3AlBr3 system期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Anomalous hydroalumination of methyl nopol ether with a LiAlH4-3AlBr3 system

Authors:	E. V. Gorobetz A. N. Kasatkin A. V. Kutchin G. A. Tolstikov

Affiliation:	(1) Ural Branch of the Russian Academy of Sciences, Institute of Organic Chemistry, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation

Abstract:	Hydroalumination of methyl nopol ether with a LiAlH₄-3AlBr₃ system is accompanied by a skeleton rearrangement and gives 6-dibromoalumo-7-methoxymethyl-2-menthene. Further hydroalumination affords a mixture of 2,6- and 2,5-bis(dibromoalumo)-7-(methoxymethyl)menthanes in 8020 ratio. Hydrolysis and oxidation of these organoaluminum compounds were carried out.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 506–510, March, 1994.

Keywords:	nopol 7-methoxymethyl-2-menthene hydroalumination oxidation rearrangement mechanism
本文献已被 SpringerLink 等数据库收录！