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Growth and characterization of l-histidine cadmium chloride monohydrate a semiorganic nonlinear optical crystals
Authors:J. Chandrasekaran  P. Ilayabarathi  P. Maadeswaran  P. Mohamed Kutty  S. Pari
Affiliation:1. Department of Physics, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore – 641 020, Tamil Nadu, India;2. Research and Development Centre, Bharathiar University, Coimbatore – 641 046, Tamil Nadu, India;3. Department of Physics, K S Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India;4. Department of Physics, National College, Tiruchirapalli – 620 001, Tamil Nadu, India;1. Crystal Growth Laboratory, PG & Research Department of Physics, Periyar EVR College (Autonomous), Tiruchirappalli, 620 023, Tamil Nadu, India;2. Crystal Growth and Thin Film Laboratory, Department of Physics and Nanotechnology, SRM University, Kattankulathur, 603 203, Kancheepuram, Tamil Nadu, India;3. Department of Bioinformatics, School of Chemical and Biotechnology, SASTRA University, Thanjavur, 613 401, India;1. Department of Physics, SRM Institute of Science and Technology, Ramapuram Campus, Chennai – 600089, Tamil Nadu, India;2. Department of Chemistry, College of Natural and Computational Sciences, Haramaya University, Dire Dawa, Ethiopia;3. Division of Physics, School of Advanced Sciences, VIT, Chennai, 600127 Tamil Nadu, India
Abstract:l-histidine cadmium chloride monohydrate (LHCCM), a semiorganic nonlinear optical material was grown from aqueous solution by slow solvent evaporation method at room temperature. The LHCCM crystals were characterized by X-ray powder diffraction analysis. The presence of functional groups was identified through fourier transform infrared spectroscopy. Thermogravimetric and differential thermal analysis confirms that the crystal is stable up to 277 °C. The dielectric constant was studied as a function of frequency for various temperatures. The mechanical properties of the grown crystals have been studied using Vickers microhardness tester. The second harmonic generation behavior of LHCCM crystal was tested by modified Kurtz–Perry powder technique.
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