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Melamine–formaldehyde resin supported H a mild and inexpensive reagent for synthesis of coumarins under mild conditions
Authors:Ramin Rezaei  Leila Dorosty  Maryam Rajabzadeh  Reza Khalifeh
Affiliation:a Department of Chemistry, Firoozabad Branch, Islamic Azad University, P. O. Box 74715-117 Firoozabad, Iran;b Department of Chemistry, Faculty of Basic Sciences, Shiraz University of Technology, Shiraz 71555-313, Iran
Abstract:Melamine–formaldehyde resin supported H+ is used as an efficient catalyst in the Pechmann condensation reaction of phenols with β-ketoesters, in solvent-free media leading to the formation of coumarin derivatives using conventional heating and microwave irradiation in excellent yields with good purity.
Keywords:Coumarins   Phenols   β-Ketoesters   Melamine&ndash  formaldehyde resin   Pechmann condensation   Solvent-free
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