Synthesis and properties of a novel redox driven chemiluminescent material built on a terthienyl system |
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| Authors: | Nurdan At?lgan Fatih Alg? Ahmet M Önal Atilla Cihaner |
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| Institution: | 1. Department of Chemistry, Middle East Technical University, TR-06531 Ankara, Turkey;2. Laboratory of Organic Materials (LOM), Çanakkale Onsekiz Mart University, TR-17100 Çanakkale, Turkey;3. Chemistry Group, Faculty of Engineering, At?l?m University, TR-06836 Ankara, Turkey |
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| Abstract: | A novel redox driven chemiluminescent material built on a terthienyl system, namely 5,7-di-ethylenedioxythiophen-2-yl-2,3-dihydro-thieno3,4-d]pyridazine-1,4-dione (ETE-Lum), which is soluble in both organic media and basic aqueous solution was synthesized and characterized. Furthermore, its polymer, PETE-Lum, which is one of the most rare examples of chemiluminescent polymeric materials bearing a pyridazine unit, was obtained successfully by electrochemical means. Both of the materials give chemiluminescence either by treatment with oxidants (H2O2 and/or KMnO4) or by the application of a potential pulse. |
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