Synthesis of racemic and optically active forms of lineatin,the unique tricyclic pheromone of trypodendron lineatum (olivier) |
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| Authors: | Kenji Mori Mitsuru Sasaki |
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| Institution: | Department of Agricultural Chemistry, The University of Tokyo, Yayoi 1-1-1, Bunkyo-ku, Tokyo 113, Japan |
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| Abstract: | (±) - 33,7 - Trimethyl - 2,9 - dioxatricyclo3.3.1.04,7]nonane 1 and (±) - 3,3,7 - trimethyl - 2,9-dioxatricyclo 4.2.1.04,7]nonane 2 were synthesized. The former was shown to be (±)-lineatin, an ambrosia beetle pheromone. A selective synthesis of (±)-lineatin was devised, which was modified to yield the both enantiomers of lineatin via optical resolution of an intermediate. |
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| Keywords: | Authors to whom correspondence should be addressed |
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