The clemmensen reaction of tigogenin. A reinvestigation |
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Authors: | Miguel Zachis Jaime A. Rabi |
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Affiliation: | Núcleo de Pesquisas de Produtos Naturais, Centro de Ciências da Saúde, Bloco H, Universidade Federal do Rio de Janeiro, Ilha do Fundão, Rio de Janeiro, Brasil |
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Abstract: | The reaction of tigogenin () with amalgamated zinc yields tetrahydrotigogenin () and the furostan . While undergoes acid catalyzed elimination to give the rearranged product , spontaneously decomposes to a mixture of and . |
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