A two-phase reaction catalyzed by a protein — asymmetric oxidation of formaldehyde dithioacetals with aqueous sodium metaperiodate |
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Authors: | Katsuyuki Ogura Makoto Fujita Hirotada Iida |
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Institution: | Department of Synthetic Chemistry, Faculty of Engineering, Chiba University, Yayoicho 1-33, Chiba 260, Japan |
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Abstract: | We examined whether a protein could catalyze two-phase oxidation of formaldehyde dithioacetals with aqueous sodium metaperiodate and bovine serum albumin was found to be effective and give the corresponding S-oxides in optically active forms. |
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