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Acid-base titrations of schiff bases in deuteriomethanol as studied by1H NMR
Authors:M. Mäkelä  O. Hormi  E. Jula  T. Korpela
Affiliation:(1) Department of Biochemistry, University of Turku, SF-20500 Turku, Finland;(2) Department of Organic Chemistry, Abo Academi, SF-20500 Turku, Finland
Abstract:
The Schiff bases of salicylaldehyde and pyridoxal 5prime-phosphate with amino compounds were studied by1H NMR in CD3OD by using a glass electrode for the control of acidity. This study makes a new contribution for the elucidation of the structures of pyridoxylidene Schiff bases and gives additional data on the1H NMR of the compounds that have not been available from the related studies in aqueous solutions.
Keywords:Pyridoxal 5  /content/x42x084628612224/xxlarge8242.gif"   alt="  prime"   align="  BASELINE"   BORDER="  0"  >-phosphate  salicylaldehyde  Schiff bases  amino acids
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