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Calix[4]arene-based metal-organic frameworks: towards hierarchically porous materials
Authors:Bew Sean P  Burrows Andrew D  Düren Tina  Mahon Mary F  Moghadam Peyman Z  Sebestyen Viorica M  Thurston Sean
Affiliation:School of Chemistry, University of East Anglia, Norwich Research Park, Norwich, NR4 7TJ, UK. s.bew@uea.ac.uk
Abstract:An upper rim-functionalised calix[4]arene dicarboxylic acid (H(2)caldc) has been used to prepare four metal-organic frameworks, three of which have been structurally characterised and shown to form two- or three-dimensional network structures. Simulations suggest that such networks are likely to display interesting selectivity to guest molecules.
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