Calix[4]arene-based metal-organic frameworks: towards hierarchically porous materials |
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Authors: | Bew Sean P Burrows Andrew D Düren Tina Mahon Mary F Moghadam Peyman Z Sebestyen Viorica M Thurston Sean |
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Affiliation: | School of Chemistry, University of East Anglia, Norwich Research Park, Norwich, NR4 7TJ, UK. s.bew@uea.ac.uk |
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Abstract: | An upper rim-functionalised calix[4]arene dicarboxylic acid (H(2)caldc) has been used to prepare four metal-organic frameworks, three of which have been structurally characterised and shown to form two- or three-dimensional network structures. Simulations suggest that such networks are likely to display interesting selectivity to guest molecules. |
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