Chiroptical properties of an alternatingly functionalized cellotriose bearing two porphyrin groups |
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| Authors: | Sakakibara Keita Nakatsubo Fumiaki French Alfred D Rosenau Thomas |
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| Institution: | Department of Chemistry, University of Natural Resources and Life Sciences (BOKU), Muthgasse 18, Vienna A-1190, Austria. sakakibara.keita.4n@kyoto-u.ac.jp |
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| Abstract: | Right-handedness derived from bisporphyrins attached to a cellotriose backbone at O-6 and O'-6 positions is revealed for the first time. This cellotriose is proposed as a model of alternatingly functionalized cellulosics, which have promising properties for applications in optoelectronics and molecular receptors owing to the chirality and rigid backbone effects. |
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